Metalloenzymes In Denitrification

Author: Isabel Moura
Publisher: Royal Society of Chemistry
ISBN: 1782623345
Size: 35.70 MB
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The importance of this pathway has inspired efforts to understand in greater depth the mechanisms involved. This book presents and discusses the latest information on multiple aspects of denitrification.

Synthesis Characterization And Reactivity Of Mononuclear Copper Nitrogen Oxide Complexes

Author: Christy Ellen Ruggiero
Publisher:
ISBN:
Size: 21.37 MB
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The effects of denitrifying bacteria can also be advantageous. They have recently
been used to reduce nitrogen oxides in emissions” and to reduce nitrates in
waste and sewage.*** Because nitrogen oxides and denitrification have such
global effects, understanding how denitrifying bacteria function is of profound
environmental importance. In denitrifying bacteria, the interconversion of all the
nitrogen oxides are carried out by metalloenzymes (Figure 1-2).” The enzyme
nitrate ...

Zeolites In Catalysis

Author: Jiří Čejka
Publisher: Royal Society of Chemistry
ISBN: 1782627847
Size: 37.96 MB
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Covering the breadth of zeolite chemistry and catalysis, this book provides the reader with a complete introduction to field, covering synthesis, structure, characterisation and applications.

Spectroscopic And Mechanistic Studies Of Copper Active Sites In Bacterial Denitrification And Cofactor Biogenesis

Author: Somdatta Ghosh
Publisher:
ISBN:
Size: 29.98 MB
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In a physiological sense, denitrification is an anaerobic analogue to dioxygen
respiration (Figure 1.3). The key enzymes in aerobic respiration are cytochrome c
or quinol oxidases acting as terminal oxidases. The NO3", NO2", NO and N2O
reductases can function as terminal oxidases collectively or individually in the
denitrification pathway. Figure 1.3. Comparison between bacterial aerobic
respiration and denitrification. Adapted from reference 1 7. 1.2.2. Metalloenzymes
Nitrate ...

Transition Metals In Microbial Metabolism

Author: Gunther Winkelmann
Publisher: CRC Press
ISBN: 9789057022203
Size: 12.39 MB
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CYTOCHROME C NITRITE REDUCTASE AND NITROUS OXIDE REDUCTASE:
TWO METALLO ENZYMES OF THE NITROGEN CYCLE WITH NOVEL METAL
SITES WOLFRAM SCHUMACHER, FRANK NEESE, URSULA HOLE and PETER
M.H. KRONECK Fakultät für Biologie, Universität Konstanz, D-78464 Konstanz,
Germany THE NITROGEN ... Dissimilatory nitrate reduction proceeds via two
different pathways, i.e. denitrification (1), and nitrate ammonification (2) (Scheme
1).

Nitrogen Cycling In Bacteria

Author: James W. B. Moir
Publisher: Horizon Scientific Press
ISBN: 1904455867
Size: 22.43 MB
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Structure,. Function,. Regulation. and. Evolution. of. the. Nitrite. and. Nitrous.
Oxide. Reductases: Denitrification. Enzymes. with. a. Beta-propeller. Fold. Figure
7.2 Reaction cycle of nitrous oxide reductase (adapted from ... The four steps
within this metabolic pathway are catalysed by the nitrate, nitrite, nitric oxide and
nitrous oxide reductases, which are complex multi-subunit metalloenzymes with
unique metal-based electron transfer pathways and catalytic sites (Berks etal.,
1995).

Molybdenum And Tungsten Enzymes

Author: Russ Hille
Publisher: Royal Society of Chemistry
ISBN: 1782628789
Size: 53.97 MB
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A particular emphasis is placed on how these important studies have been used to reveal critical components of enzyme mechanisms.This text will be a valuable reference to workers both inside and outside the field, including graduate ...

Bioinorganic Chemistry Inorganic Elements In The Chemistry Of Life

Author: Wolfgang Kaim
Publisher: Wiley
ISBN: 9780471943686
Size: 79.85 MB
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Aerobic conditions and sufficient buffer capacity for the resulting protons in soil or
mineral material (atmospheric weathering) are indispensable. Some
metalloenzymes for certain stages of ^nitrification, a process which is gaining
importance for ecological reasons [27], have already been introduced: the
molybdenum-containing nitrate(N+v) reductase (-» nitrite), the copper or heme-
iron containing nitrite(N+i") reductases (see Section 6.5 and 10.3), and the
copper-containing dinitrogen ...

Annual Review

Author:
Publisher:
ISBN:
Size: 27.68 MB
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The reverse process of the nitrogen fixing is called denitrification process. In this
process, nitrate or nitrite ion is reduced to nitrogen gas via nitric oxide and nitrous
oxide by many metalloenzymes, nitrate reducatse, nitrite reductase, nitric oxide
reductase, and nitrous oxide reductase. In this project, we are studying the
molecular mechanism of these metalloenzymes relating to the denitrification
process. these copper(I) carbonyl complexes do not show any evidence of. probe
to study the ...

Synthetic Modeling Of Copper Proteins Involved In Respiration And Other Related Functions

Author: Jamie Lynn Schneider
Publisher:
ISBN:
Size: 46.29 MB
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Small, discrete model complexes and derived intermediates generally can be
more readily characterized with higher resolution by a variety of spectroscopic
and analytical techniques as compared to metalloproteins. 1.2 Anaerobic
Respiration: Denitrification Many bacteria and fungi can survive in dioxygen free
environments (anaerobic environments) by utilizing nitrogen oxides instead of
dioxygen to produce energy and therefore support cell growth. During this
anaerobic respiration ...